Demineralization of organic pollutants on the dye modified TiO2 semiconductor particulate system using visible light

被引:185
作者
Chatterjee, D [1 ]
Mahata, A [1 ]
机构
[1] Cent Mech Engn Res Inst, Chem Sect, Durgapur 713209, India
关键词
photodegradation; dye sensitization; TiO2; photocatalyst; organic pollutants; visible light; thionine; eosin Y;
D O I
10.1016/S0926-3373(01)00170-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photodegradation of organic pollutants, viz. phenol, chlorophenol, 1,2-dichloroethane and trichloroethylene in water has been achieved on the surface of TiO2 semiconductor modified with thionine and eosin Y by using visible light. After 5 h of irradiation with a 50 W tungsten lamp, over 55-72% degradation of pollutants is achieved. A working mechanism involving excitation of surface bound dye, followed by charge injection into the TiO2 conduction band is proposed. (C) 2001 Elsevier Science B.V All rights reserved.
引用
收藏
页码:119 / 125
页数:7
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