Palladium β-diiminate chemistry: Reactivity towards monodentate ligands and arylboronic acids

被引：11

作者：

Annibale, Vincent T. ^{[1
]}

Tan, Runyu ^{[1
]}

Janetzko, John ^{[1
]}

Lund, Liisa M. ^{[1
]}

Song, Datong ^{[1
]}

机构：

[1] Univ Toronto, Davenport Chem Res Labs, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

INORGANICA CHIMICA ACTA | 2012年 / 380卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

beta-Diiminate ligands; Palladium; Reactivity; Monodentate ligands; Boronic acids; Nacnac; DIKETIMINATE LIGAND; REDUCTIVE ELIMINATION; COMPLEXES; POLYMERIZATION; PLATINUM(II); DERIVATIVES; ACTIVATION; PRECURSORS; DINUCLEAR; NICKEL;

D O I：

10.1016/j.ica.2011.09.044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Here we report the synthesis and characterization of a series of palladium beta-diiminate complexes. Chloro-bridged dimers [Pd(Ar(2)nacnac)(mu-Cl)](2) (where [Ar(2)nacnac] is [(ArNC(CH3))(2)CH] with Ar being aryl substituents) can serve as versatile starting materials, and can be cleaved by neutral monodentate ligands (L) to form mononuclear complexes [Pd(Ar(2)nacnac)(L)Cl], or engage in unusual transmetallation reactions with boronic acids to form tetrapallada-macrocycles. The reactivity of the tetrapallada-macrocyclic complexes towards L-type ligands, as well as the reactivity of Pd(Ar(2)nacnac)(L)Cl] complexes towards boronic acids was also also explored. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：308 / 321

页数：14

共 42 条

[1] BIS(BENZONITRILE)DICHLORO COMPLEXES OF PALLADIUM AND PLATINUM [J].

ANDERSON, GK ;

LIN, M .

INORGANIC SYNTHESES, 1990, 28 :60-63

[2] Unusual transmetallation-induced formation of a C2-symmetric tetrapallada-macrocycle [J].

Annibale, Vincent T. ;

Lund, Liisa M. ;

Song, Datong .

CHEMICAL COMMUNICATIONS, 2010, 46 (43) :8261-8263

[3] Nickel α-Keto-β-Diimine Initiators for Olefin Polymerization [J].

Azoulay, Jason D. ;

Rojas, Rene S. ;

Serrano, Abigail V. ;

Ohtaki, Hisashi ;

Galland, Griselda B. ;

Wu, Guang ;

Bazan, Guillermo C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (06) :1089-1092

[4] Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes [J].

Barrios-Landeros, Fabiola ;

Carrow, Brad P. ;

Hartwig, John F. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (23) :8141-8154

[5] Palladium(II) complexes with pentafluorophenyl ligands: structures, C6F5 fluxionality by 2D-NMR studies and pre-catalysts for the vinyl addition polymerization of norbornene [J].

Blank, Frederik ;

Scherer, Harald ;

Ruiz, Jose ;

Rodriguez, Venancio ;

Janiak, Christoph .

DALTON TRANSACTIONS, 2010, 39 (15) :3609-3619

[6] The chemistry of β-diketiminatometal complexes [J].

Bourget-Merle, L ;

Lappert, MF ;

Severn, JR .

CHEMICAL REVIEWS, 2002, 102 (09) :3031-3065

[7]

*BRUK AXS INC, 2008, AP 2 SOFTW PACK

[8] Gas-Phase Energetics of Reductive Elimination from a Palladium(II) N-Heterocyclic Carbene Complex [J].

Couzijn, Erik P. A. ;

Zocher, Eva ;

Bach, Andreas ;

Chen, Peter .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (18) :5408-5415

[9]

Crabtree RH, 2005, ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS, 4TH EDITION, P1, DOI 10.1002/0471718769

[10] 3,5-dichlorotrifluorophenyl complexes, aryl derivatives with simple 19F NMR structural probes.: The synthesis of general precursors for Pd- and Pt complexes [J].

Espinet, P ;

Martinez-Ilarduya, JM ;

Perez-Briso, C ;

Casado, AL ;

Alonso, MA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 551 (1-2) :9-20

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