Porphyrin-containing D-π-A conjugated polymer with absorption over the entire spectrum of visible light and its applications in solar cells

被引：32

作者：

Shi, Shaowei ^{[1
]}

Wang, Xiaochen ^{[1
]}

Sun, Yeping ^{[1
,2
]}

Chen, Song ^{[3
]}

Li, Xiaoyu ^{[1
]}

Li, Yongfang ^{[2
]}

Wang, Haiqiao ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composite, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China

[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China

[3] China Text Acad, Beijing 100025, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 22期

基金：

北京市自然科学基金;

关键词：

PHOTOVOLTAIC PROPERTIES; ORGANIC PHOTOVOLTAICS; FULLERENE; ACCEPTOR; UNITS; COPOLYMERS; DESIGN; DONOR;

D O I：

10.1039/c2jm31649h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this communication, we present the first example of a donor-acceptor porphyrin-containing conjugated copolymer, PCTTQP, with absorption over the entire spectrum of visible light. The BHJ solar cells based on PCTTQP : PC71BM blends displayed a PCE of 2.5%, which is the highest value in porphyrin-based conjugated polymers.

引用

页码：11006 / 11008

页数：3

共 29 条

[1]

Akita M., 2012, ANGEW CHEM INT EDIT, V51, P1

[2] Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].

Anderson, HL .

CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330

[3] Tailoring porphyrins and chlorins for self-assembly in biomimetic artificial antenna systems [J].

Balaban, TS .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :612-623

[4] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].

Blouin, Nicolas ;

Michaud, Alexandre ;

Gendron, David ;

Wakim, Salem ;

Blair, Emily ;

Neagu-Plesu, Rodica ;

Belletete, Michel ;

Durocher, Gilles ;

Tao, Ye ;

Leclerc, Mario .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742

[5] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[6] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[7] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Dennler, Gilles ;

Scharber, Markus C. ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2009, 21 (13) :1323-1338

[8] Porphyrin-dithienothiophene π-conjugated copolymers:: Synthesis and their applications in field-effect transistors and solar cells [J].

Huang, Xuebin ;

Zhu, Chunli ;

Zhang, Shiming ;

Li, Weiwei ;

Guo, Yunlong ;

Zhan, Xiaowei ;

Liu, Yunqi ;

Bo, Zhishan .

MACROMOLECULES, 2008, 41 (19) :6895-6902

[9] Giant multiporphyrin arrays as artificial light-harvesting antennas [J].

Imahori, H .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (20) :6130-6143

[10] Porphyrin-diones and porphyrin-tetraones: Reversible redox units being localized within the porphyrin macrocycle and their effect on tautomerism [J].

Kadish, Karl M. ;

E, Wenbo ;

Zhan, Riqiang ;

Khoury, Tony ;

Govenlock, Linda J. ;

Prashar, Jognandan K. ;

Sintic, Paul J. ;

Ohkubo, Kei ;

Fukuzumi, Shunichi ;

Crossley, Maxwell J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) :6576-6588

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