Intercalation Reaction of Carbonate MgAl-layered Double Hydroxide Using Alcohol as Solvent

被引:17
作者
Hayashi, Aki [1 ]
Nakayama, Hirokazu [1 ]
机构
[1] Kobe Pharmaceut Univ, Dept Funct Mol Chem, Kobe, Hyogo 6588558, Japan
关键词
HYDROTALCITE-LIKE COMPOUNDS; SOLVOTHERMAL ION-EXCHANGE; MIXED-SOLUTION; DECARBONATION; ACID; LDHS; DEINTERCALATION; ANIONS;
D O I
10.1246/cl.2011.276
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We succeeded in the first direct intercalation of an organic compound into carbonate layered double hydroxide (LDH) by using alcohol as the solvent at 50 degrees C. Furthermore, carbonate ion in carbonate LDH was easily exchanged with chloride or nitrate ion in methanol.
引用
收藏
页码:276 / 278
页数:3
相关论文
共 21 条
[1]  
Cardoso LP, 2003, MOL CRYST LIQ CRYST, V390, P49, DOI [10.1080/10587250216162, 10.1080/15421400390193404]
[2]   REACTION OF MOLTEN SEBACIC ACID WITH A LAYERED (MG/AL) DOUBLE HYDROXIDE [J].
CARLINO, S ;
HUDSON, MJ .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (01) :99-104
[3]   The reaction of molten phenylphosphonic acid with a layered double hydroxide and its calcined oxide [J].
Carlino, S ;
Hudson, MJ ;
Husain, SW ;
Knowles, JA .
SOLID STATE IONICS, 1996, 84 (1-2) :117-129
[4]   INTERCALATION OF ORGANIC AND INORGANIC ANIONS INTO LAYERED DOUBLE HYDROXIDES [J].
CHIBWE, K ;
JONES, W .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) :926-927
[5]  
Fogg AM, 1999, ADV MATER, V11, P1466, DOI 10.1002/(SICI)1521-4095(199912)11:17<1466::AID-ADMA1466>3.0.CO
[6]  
2-1
[7]   Evidences for decarbonation and exfoliation of layered double hydroxide in N,N-dimethylformamide-ethanol solvent mixture [J].
Gordijo, Claudia R. ;
Constantino, Vera R. Leopoldo ;
Silva, Denise de Oliveira .
JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (07) :1967-1976
[8]   THE USE OF GLYCEROL INTERCALATES IN THE EXCHANGE OF CO32- WITH SO42-, NO-3(-) OR CL- IN PYROAURITE-TYPE COMPOUNDS [J].
HANSEN, HCB ;
TAYLOR, RM .
CLAY MINERALS, 1991, 26 (03) :311-327
[9]   Effects of anion species on deintercalation of carbonate ions from hydrotalcite-like compounds [J].
Iyi, N ;
Okamoto, K ;
Kaneko, Y ;
Matsumoto, T .
CHEMISTRY LETTERS, 2005, 34 (07) :932-933
[10]   Deintercalation of carbonate ions from a hydrotalcite-like compound: Enhanced decarbonation using acid-salt mixed solution [J].
Iyi, N ;
Matsumoto, T ;
Kaneko, Y ;
Kitamura, K .
CHEMISTRY OF MATERIALS, 2004, 16 (15) :2926-2932