Highly electrophilic lanthanide complexes containing fluorinated amido ligands:: multiple Ln-F interactions, agostic interactions and η6-arene coordination

被引:52
作者
Click, DR [1 ]
Scott, BL [1 ]
Watkin, JG [1 ]
机构
[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA
关键词
D O I
10.1039/a809275c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly fluorinated amido ligands have been employed as supporting ligands for homoleptic lanthanide complexes; Xray diffraction studies reveal multiple Ln ... F interactions and a rare example of an eta(6)-bound toluene solvent molecule.
引用
收藏
页码:633 / 634
页数:2
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