Phosphine-based coordination cages and nanoporous coordination polymers

被引：17

作者：

James, SL

Xu, XL

Law, RV

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 196卷

关键词：

cage; coordination; phosphine; polymer; porous; silver;

D O I：

10.1002/masy.200390159

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recent findings in the use of multidentate phosphines to synthesise porous coordination polymers (metal-organic frameworks) and their possible precursor cages are reviewed. Additional recent investigations into using large adamantoid Ag-6 cages as polymer vertices in giant diamandoid structures are also presented. The results are discussed in terms of possible strategies for the controled synthesis of porous coordination polymers.

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收藏

页码：187 / 199

页数：13

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