Sulfonated carbon nanotubes as a strong protonic acid catalyst

被引：133

作者：

Peng, F ^{[1
]}

Zhang, L ^{[1
]}

Wang, HJ ^{[1
]}

Lv, P ^{[1
]}

Yu, H ^{[1
]}

机构：

[1] S China Univ Technol, Dept Chem Engn, Guangzhou 510640, Peoples R China

来源：

CARBON | 2005年 / 43卷 / 11期

关键词：

chemically modified carbons; surface treatment; adsorption; reactivity;

D O I：

10.1016/j.carbon.2005.04.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfonated carbon nanotubes with a high density of sulfonic acid groups were prepared by reacting concentrated sulfuric acid with multiwall carbon nanotubes at high temperature. Activated carbon was treated by the concentrated sulfuric acid by the same procedure used for the preparation of H 2SO4-treated CNTs to obtain acidified activated carbon. SEM-EDS images of H2SO4-treated CNTs showed that morphology and structure of the carbon nanotubes did not change after sulfonation with concentrated sulfuric acid at high temperature.

引用

页码：2405 / 2408

页数：4

共 14 条

[1] Fabrication of high performance carbon nanotube field emitters [J].

Choi, GS ;

Son, KH ;

Kim, DJ .

MICROELECTRONIC ENGINEERING, 2003, 66 (1-4) :206-212

[2] Nanotubes as nanoprobes in scanning probe microscopy [J].

Dai, HJ ;

Hafner, JH ;

Rinzler, AG ;

Colbert, DT ;

Smalley, RE .

NATURE, 1996, 384 (6605) :147-150

[3] Electrical conductivity of individual carbon nanotubes [J].

Ebbesen, TW ;

Lezec, HJ ;

Hiura, H ;

Bennett, JW ;

Ghaemi, HF ;

Thio, T .

NATURE, 1996, 382 (6586) :54-56

[4] Surface modification of multiwalled carbon nanotubes: Toward the tailoring of the interface in polymer composites [J].

Eitan, A ;

Jiang, KY ;

Dukes, D ;

Andrews, R ;

Schadler, LS .

CHEMISTRY OF MATERIALS, 2003, 15 (16) :3198-3201

[5] Electrochemical studies of single-wall carbon nanotubes as nanometer-sized activators in enzyme-catalyzed reaction [J].

Gan, ZH ;

Zhao, Q ;

Gu, ZN ;

Zhuang, QK .

ANALYTICA CHIMICA ACTA, 2004, 511 (02) :239-247

[6] A carbon material as a strong protonic acid [J].

Hara, M ;

Yoshida, T ;

Takagaki, A ;

Takata, T ;

Kondo, JN ;

Hayashi, S ;

Domen, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2955-2958

[7] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[8] Selective attachment of gold nanoparticles to nitrogen-doped carbon nanotubes [J].

Jiang, KY ;

Eitan, A ;

Schadler, LS ;

Ajayan, PM ;

Siegel, RW ;

Grobert, N ;

Mayne, M ;

Reyes-Reyes, M ;

Terrones, H ;

Terrones, M .

NANO LETTERS, 2003, 3 (03) :275-277

[9] Modified carbon nanotubes: an effective way to selective attachment of gold nanoparticles [J].

Jiang, LQ ;

Gao, L .

CARBON, 2003, 41 (15) :2923-2929

[10] Hydrogen storage in solar produced single-walled carbon nanotubes [J].

Luxembourg, D ;

Flamant, G ;

Guillot, A ;

Laplaze, D .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 108 (1-2) :114-119

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