Investigation of a new pathway forming naphthalene by the recombination reaction of cyclopentadienyl radicals

被引：16

作者：

Murakami, Y ^{[1
]}

Saejung, T

Ohashi, C

Fujii, N

机构：

[1] Nagaoka Univ Technol, Dept Chem, Nagaoka, Niigata 9402188, Japan

[2] Niigata Sangyo Univ, Life Engn Ctr, Niigata 9451395, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 12期

关键词：

D O I：

10.1246/cl.2003.1112

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanism of naphthalene (c-C10H8) formation by the recombination of cyclopentadienyl radicals (C-C5H5) was investigated by monitoring the time profiles of H atom behind the reflected shock of trifluoromethoxybenzene (C6H5OCF3) highly diluted with Ar. The rate constant for C-C5H5 + C-C5H5 --> c-C10H8 + 2H was determined to be 3.3 x 10(17) exp(-135 kJ/ RT) cm(3) mol(-1) s(-1).

引用

页码：1112 / 1113

页数：2

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