Polymer-supported organic catalysts

被引：731

作者：

Benaglia, M

Puglisi, A

Cozzi, F

机构：

[1] CNR, ISTM, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

[2] Ctr Eccellenza CISI, I-20133 Milan, Italy

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 09期

关键词：

D O I：

10.1021/cr010440o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review describes how, in less than 25 years, polymer-supported organic catalysts have turned from chemical curiosities into powerful synthetic tools readily available to the chemical community. Whenever possible, comparison between the behavior of supported versus nonsupported catalyst is attempted. Particular attention is devoted to catalyst recovery and recycling. The discussion on the structure of the polymeric support is limited to those examples for which its influence on the catalyst performance has been clearly demonstrated.

引用

收藏

页码：3401 / 3429

页数：29

相关论文

共 235 条

[1] Improved procedure for Julia-Colonna asymmetric epoxidation of α,β-unsaturated ketones:: total synthesis of diltiazem and Taxol™ side-chain [J].

Adger, BM ;

Barkley, JV ;

Bergeron, S ;

Cappi, MW ;

Flowerdew, BE ;

Jackson, MP ;

McCague, R ;

Nugent, TC ;

Roberts, SM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (23) :3501-3507

[2] New strategies for organic catalysis: The first highly enantioselective organocatalytic Diels-Alder reaction [J].

Ahrendt, KA ;

Borths, CJ ;

MacMillan, DWC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (17) :4243-4244

[3] Use of a quaternary ammonium salt supported on a liposoluble poly(ethylene glycol) matrix for laboratory and industrial synthetic applications of phase-transfer catalysis [J].

Albanese, D ;

Benaglia, M ;

Landini, D ;

Maia, A ;

Lupi, V ;

Penso, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (20) :4928-4935

[4] Polyamino acid-catalysed asymmetric epoxidation: Sodium percarbonate as a source of base and oxidant [J].

Allen, JV ;

Drauz, KH ;

Flood, RW ;

Roberts, SM ;

Skidmore, J .

TETRAHEDRON LETTERS, 1999, 40 (29) :5417-5420

[5] Julia-Colonna asymmetric epoxidation reactions under non-aqueous conditions: Rapid, highly regio- and stereo-selective transformations using a cheap, recyclable catalyst [J].

Allen, JV ;

Bergeron, S ;

Griffiths, MJ ;

Mukherjee, S ;

Roberts, SM ;

Williamson, NM ;

Wu, LE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (19) :3171-3179

[6] New polymer-supported catalysts derived from Cinchona alkaloids:: Their use in the asymmetric Michael reaction [J].

Alvarez, R ;

Hourdin, MA ;

Cavé, C ;

d'Angelo, J ;

Chaminade, P .

TETRAHEDRON LETTERS, 1999, 40 (39) :7091-7094

[7]

Anelli P. L., 1990, ORG SYNTH, V69, P212

[8] POLYMER-SUPPORTED CRYPTANDS - PROBLEMS ARISING IN THE SYNTHESIS OF HIGHLY LOADED POLYMERS [J].

ANELLI, PL ;

MONTANARI, F ;

QUICI, S .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (25) :4910-4914

[9]

ANELLI PL, 1986, GAZZ CHIM ITAL, V116, P127

[10] INFLUENCE OF SPACER CHAINS AND PERCENTAGE RING SUBSTITUTION ON PHASE-TRANSFER CATALYTIC ACTIVITY OF PHOSPHONIUM SALTS BONDED TO POLYSTYRENE MATRIX [J].

ANELLI, PL ;

MONTANARI, F ;

QUICI, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (12) :1827-1830

← 1 2 3 4 5 6 7 8 9 10 →