Improvement of the microactivity test for kinetic and deactivation studies involved in catalytic cracking

被引:38
作者
Delattre, C
Forissier, M
Pitault, I
Schweich, D
Bernard, JR
机构
[1] CPE Lyon, Lab Genie Proc Catalyt, F-69223 Villeurbanne, France
[2] Ctr Rech Elf Solaize, F-69360 Solaize, France
关键词
catalytic cracking; kinetics; deactivation; parameter identification; petroleum; modeling;
D O I
10.1016/S0009-2509(00)00356-0
中图分类号
TQ [化学工业];
学科分类号
0817 [化学工程与技术];
摘要
A new method is proposed to determine the fluid catalytic cracking catalyst deactivation and kinetic parameters of a 6-lump model of catalytic cracking, using few microactivity test (MAT) experiments. instantaneous pressure drop and outlet gas flow rare are recorded during the test. The parameters of the deactivation functions. related to catalyst coke content, are obtained using these data, a simple kinetic model and a reactor model. These functions greatly depend on the catalyst nature and reaction temperature. This method allows us to adjust non-correlated deactivation function and kinetic parameters. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1337 / 1345
页数:9
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