Direct determination of the chirality of organic molecules by scanning tunneling microscopy

被引：104

作者：

Fang, HB

Giancarlo, LC

Flynn, GW ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

[2] Columbia Univ, Columbia Radiat Lab, New York, NY 10027 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1998年 / 102卷 / 38期

关键词：

D O I：

10.1021/jp981960z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Scanning tunneling microscopy (STM) has been used to study the chiral molecules (R)/(S)-2-bromohexadecanoic acid at the liquid/solid interface. When adsorbed onto the basal plane of graphite, these molecules segregate on the surface into domains of pure R or S enantiomers. The atomic resolution obtained in the STM images of these species allows a direct assignment of the chirality of individual molecules.

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页码：7311 / 7315

页数：5

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