A biomimetic cellulose I nanolayer with a parallel chain alignment was successfully designed through the chemoselective modification of cellulose and self-assembly of its thiosemicarbazone on a gold substrate (see figure). This is the first time replication of the crystalline structure of native cellulose, that is, cellulose I, in the layer state has been achieved.
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[1]
ATALLA RH, 1984, SCIENCE, V223, P283, DOI 10.1126/science.223.4633.283