Molecular riveting: High yield preparation of a [3]-rotaxane

被引:104
作者
Kolchinski, AG
Alcock, NW
Roesner, RA
Busch, DH [1 ]
机构
[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
关键词
D O I
10.1039/a800639c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An aminothiol axle molecule is so efficient at threading through the macrocycle 24-crown-8 that iodine oxidation produces a [3]-rotaxane in record yield (84%) by literally riveting two rings together.
引用
收藏
页码:1437 / 1438
页数:2
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