Perfectly polar assembly of molecular dipoles in crystals of Zn(II)(DMAP)(acac)2:: a case of self-poling

被引：29

作者：

Anthong, SP ^{[1
]}

Radhakrishnan, TP ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 10期

关键词：

D O I：

10.1039/b101248g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular dipoles assemble with a perfectly polar alignment in the crystals of the title complex and the hierarchy of intermolecular interactions in the lattice adheres to the requirements of a previously reported stochastic model for the production of polarity in supramolecular assemblies.

引用

页码：931 / 932

页数：2

共 25 条

[1]

[Anonymous], POLED POLYM THEIR AP

[2]

BOSSHARD C, 1991, CRYSTAL ENG MOL CRYS, P261

[3]

Bosshard C., 1997, NONLINEAR OPTICS ORG, P391

[4]

CHEMLA DS, 1989, NONLINEAR OPTICAL PR, V1, P2

[5] The C-H center dot center dot center dot O hydrogen bond: Structural implications and supramolecular design [J].

Desiraju, GR .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (09) :441-449

[6] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[7] Influence of alkyl chain length on the crystal structures and optical SHG of N-n-alkyl-2,4-dinitroanilines:: Role of dipolar and dispersion energies [J].

Gangopadhyay, P ;

Radhakrishnan, TP .

CHEMISTRY OF MATERIALS, 2000, 12 (11) :3362-3368

[8] Crystallization of supramolecular materials: Perhydrotriphenylene (PHTP) inclusion compounds with nonlinear optical properties [J].

Hoss, R ;

Konig, O ;

KramerHoss, V ;

Berger, U ;

Rogin, P ;

Hulliger, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (15) :1664-1666

[9] POLAR INCLUSION-COMPOUNDS OF PERHYDROTRIPHENYLENE (PHTP) AND EFFICIENT NONLINEAR-OPTICAL MOLECULES [J].

HULLIGER, J ;

KONIG, O ;

HOSS, R .

ADVANCED MATERIALS, 1995, 7 (08) :719-721

[10] A new design strategy for efficient electro-optic single-component organic crystals [J].

Hulliger, J ;

Langley, PJ ;

Roth, SW .

MATERIALS RESEARCH BULLETIN, 1998, :177-189

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