Primary charge separation in photoinduced multielectron storage systems.: A dinuclear ruthenium(II) species featuring a charge-separated state with a lifetime of 1.3 μs

被引：38

作者：

Chiorboli, C

Fracasso, S

Scandola, F

Campagna, S

Serroni, S

Konduri, R

MacDonnell, FM

机构：

[1] ISOF, CNR, Sez Ferrara, I-44100 Ferrara, Italy

[2] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

[3] INSTM UdR Ferrara, I-44100 Ferrara, Italy

[4] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

[5] INSTM UdR Messina, I-98166 Messina, Italy

[6] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b302962j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The primary photoinduced charge separation and recombination processes occurring in a dinuclear Ru(II) complex capable to perform multielectron storage upon light excitation have been studied in different solvents: the charge-separated state obtained in dichloromethane is, to the best of our knowledge, the longest-lived ever reported for a ruthenium polypyridine complex.

引用

页码：1658 / 1659

页数：2

共 28 条

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