A regenerative chemodosimeter based on metal-induced dye formation for the highly selective and sensitive optical determination of Hg2+ ions

被引:346
作者
Ros-Lis, JV
Marcos, MD
Mártinez-Máñez, R
Rurack, K
Soto, J
机构
[1] Univ Politecn Valencia, Dept Quim, Ctr Invest Quim Mol Aplicada, Valencia 46071, Spain
[2] BAM, D-12489 Berlin, Germany
关键词
chemodosimeter; dyes; fluorometric analysis; mercury; spectrophotometric analysis;
D O I
10.1002/anie.200500583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Into the blue: Hg2+-ion-triggered formation of a brightly fluorescent squaraine dye is used as a novel approach for the design of highly selective and sensitive chromofluorogenic probes for the analysis of Hg2+ ions down to concentrations below 2 ppb (see picture). Through the adsorption of the sensor on a solid support a prototype reusable test strip is also generated. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4405 / 4407
页数:3
相关论文
共 33 条
[1]  
[Anonymous], 2001, ANGEW CHEM, V113, P2710
[2]   FLUOROMETRIC CHEMODOSIMETRY - MERCURY(II) AND SILVER(I) INDICATION IN WATER VIA ENHANCED FLUORESCENCE SIGNALING [J].
CHAE, MY ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9704-9705
[3]   Photophysical properties of squaraine derivatives: Evidence for charge separation [J].
CornelissenGude, C ;
Rettig, W ;
Lapouyade, R .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (50) :9673-9677
[4]   PHOTOCHEMISTRY OF SQUARAINE DYES .8. PHOTOPHYSICAL PROPERTIES OF CROWN-ETHER SQUARAINE FLUOROIONOPHORES AND THEIR METAL-ION COMPLEXES [J].
DAS, S ;
THOMAS, KG ;
THOMAS, KJ ;
KAMAT, PV ;
GEORGE, MV .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (37) :9291-9296
[5]   Coupling selectivity with sensitivity in an integrated chemosensor framework:: Design of a Hg2+-responsive probe, operating above 500 nm [J].
Descalzo, AB ;
Martínez-Máñez, R ;
Radeglia, R ;
Rurack, K ;
Soto, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3418-3419
[6]   Differentiating natural and anthropogenic sources of metals to the environment [J].
Dias, GM ;
Edwards, GC .
HUMAN AND ECOLOGICAL RISK ASSESSMENT, 2003, 9 (04) :699-721
[7]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387
[8]   A highly selective and sensitive fluorescent chemosensor for Hg2+ in neutral buffer aqueous solution [J].
Guo, XF ;
Qian, XH ;
Jia, LH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) :2272-2273
[9]  
Kim T.-H., 2003, Angew. Chem, V115, P4951, DOI [10.1002/ange.200352075, DOI 10.1002/ANGE.200352075]
[10]   A fluorescent self-amplifying wavelength-responsive sensory polymer for fluoride ions [J].
Kim, TH ;
Swager, TM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (39) :4803-4806