Simple integral equation for the polymer brush

被引:21
作者
Orland, H
Schick, M
机构
[1] UNIV WASHINGTON,DEPT PHYS,SEATTLE,WA 98195
[2] UNIV CERGY PONTOISE,GRP PHYS STAT,F-95806 CERGY,FRANCE
[3] CE SACLAY,SERV PHYS THEOR,CEA,F-91191 GIF SUR YVETTE,FRANCE
关键词
D O I
10.1021/ma9508461
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Employing a self-consistent mean field theory approach, we consider the density profile of a polymer brush. We express the self-consistent equation in terms of the monomer density and, by considering only a restricted set of polymer trajectories, reduce it to a relatively simple integral equation for the density profile. We find rather good agreement between the solution of our equation and that of the original one over almost the whole profile range. In particular, the profile reproduces well the smooth decay of the monomer density at the free surface of the brush and in this regard is an improvement over the classical parabolic profile.
引用
收藏
页码:713 / 717
页数:5
相关论文
共 20 条
[1]   POLYMER ADSORPTION ON SMALL SPHERES - SCALING APPROACH [J].
ALEXANDER, S .
JOURNAL DE PHYSIQUE, 1977, 38 (08) :977-981
[2]   STRUCTURES OF END-GRAFTED POLYMER LAYERS - A SMALL-ANGLE NEUTRON-SCATTERING STUDY [J].
AUROY, P ;
AUVRAY, L ;
LEGER, L .
MACROMOLECULES, 1991, 24 (09) :2523-2528
[3]   STATISTICAL THERMODYNAMIC THEORY OF GRAFTED POLYMERIC LAYERS [J].
CARIGNANO, MA ;
SZLEIFER, I .
JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (06) :5006-5018
[4]   PRESSURE ISOTHERMS, PHASE-TRANSITION, INSTABILITY, AND STRUCTURE OF TETHERED POLYMERS IN GOOD, THETA, AND POOR SOLVENTS [J].
CARIGNANO, MA ;
SZLEIFER, I .
JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (04) :3210-3223
[5]   DENSITY PROFILE OF TERMINALLY ANCHORED POLYMER-CHAINS - A MONTE-CARLO STUDY [J].
CHAKRABARTI, A ;
TORAL, R .
MACROMOLECULES, 1990, 23 (07) :2016-2021
[6]   CONFIGURATION OF TERMINALLY ATTACHED CHAINS AT THE SOLID SOLVENT INTERFACE - SELF-CONSISTENT FIELD-THEORY AND A MONTE-CARLO MODEL [J].
COSGROVE, T ;
HEATH, T ;
VANLENT, B ;
LEERMAKERS, F ;
SCHEUTJENS, J .
MACROMOLECULES, 1987, 20 (07) :1692-1696
[7]  
DEGENNES PG, 1976, J PHYS LES ULIS, V37, P1443
[8]   EFFECT OF EXCLUDED VOLUME ON POLYMER DISPERSANT ACTION [J].
DOLAN, AK ;
EDWARDS, SF .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1975, 343 (1635) :427-442
[9]   STATISTICAL MECHANICS OF POLYMERS WITH EXCLUDED VOLUME [J].
EDWARDS, SF .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1965, 85 (546P) :613-&
[10]   BLOCK COPOLYMER THEORY .5. SPHERICAL DOMAINS [J].
HELFAND, E ;
WASSERMAN, ZR .
MACROMOLECULES, 1978, 11 (05) :960-966