Influence of the starting kaolin on alkali-activated materials based on metakaolin. Study of the reaction parameters by isothermal conduction calorimetry

被引:130
作者
Granizo, ML [1 ]
Blanco-Varela, MT [1 ]
Palomo, A [1 ]
机构
[1] CSIC, Madrid 28080, Spain
关键词
D O I
10.1023/A:1026790924882
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The properties of the product obtained through alkaline activation of metakaolin are directly influenced by the characteristics of the starting kaolin. For the study of this influence, a complete characterization of two spanish kaolins used to synthesised the material has been carried out. A JAF conduction calorimeter was used to follow metakaolin reaction with NaOH solutions. Calorimetric data were obtained isothermally at 45 degreesC with variable solution/solid ratio and NaOH solution concentrations varying from 12 to 18 M. (C) 2000 Kluwer Academic Publishers.
引用
收藏
页码:6309 / 6315
页数:7
相关论文
共 16 条
[1]   CRITERIA FOR THE CHARACTERIZATION OF KAOLINITE, HALLOYSITE, AND A RELATED MINERAL IN CLAYS AND SOILS [J].
BRAMAO, L ;
CADY, JG ;
HENDRICKS, SB ;
SWERDLOW, M .
SOIL SCIENCE, 1952, 73 (04) :273-287
[2]  
BRINDLEY GW, 1970, AM MINERAL, V55, P1259
[3]  
Davidovits J., 1985, USA Patent, Patent No. [45,009,985, 45009985]
[4]  
DELUXAN MP, 1974, IL CEMENTO, V71, P113
[5]   Alkaline activation of metakaolin - An isothermal conduction calorimetry study [J].
Granizo, ML ;
Blanco, MT .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1998, 52 (03) :957-965
[6]  
GRANIZO ML, 10 INT C CHEM CEM GO, V3, P8
[7]  
HINCKLEY DN, 11 NAT C CLAYS CLAY
[8]  
JOHNSON HB, 1968, J AM CERAM SOC, V52, P199
[9]   SI-29 AND AL-27 NMR-STUDY OF ZEOLITE FORMATION FROM ALKALI-LEACHED KAOLINITES - INFLUENCE OF THERMAL PREACTIVATION [J].
MADANI, A ;
AZNAR, A ;
SANZ, J ;
SERRATOSA, JM .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (02) :760-765