Transition-metal complex-catalyzed reduction of amides with hydrosilanes: a facile transformation of amides to amines

被引：124

作者：

Igarashi, M ^{[1
]}

Fuchikami, T ^{[1
]}

机构：

[1] Sagami Chem Res Ctr, Sagamihara, Kanagawa 2290012, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

transition metals; catalysts; reduction; silicon and compounds; amides; amines;

D O I：

10.1016/S0040-4039(01)00039-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of amides with hydrosilanes is catalyzed by a variety of transition-metal complexes in the presence or absence of halides and amines as co-catalysts to afford the corresponding amines in good yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1945 / 1947

页数：3

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