Five diterpenoid alkaloids from Delphinium cardiopetalum

被引:15
作者
Reina, M [1 ]
Madinaveitia, A [1 ]
Gavin, JA [1 ]
DeLaFuente, G [1 ]
机构
[1] UNIV LA LAGUNA,CSIC,CPNO ANTONIO GONZALEZ,INST PROD NAT & AGROBIOL,E-38206 LA LAGUNA,SPAIN
关键词
Delphinium cardioptelatum; ranunculaceae; diterpenoid alkaloids; cardiopine; cardiopinine; cardiopimine; cardiopidine; cardiodine;
D O I
10.1016/0031-9422(95)00756-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A further study of the alkaloidal constituents of Delphinium cardiopetalum led to the isolation of five new highly functionalized diterpenoid alkaloids, cardiopine, cardiopinine, cardiopimine, cardiopidine and cardiodine. Their structures were established by 1D and 2D NMR spectroscopy, (HCOSY)-H-1, HMQC, HMBC and ROESY, and chemical transformations.
引用
收藏
页码:1235 / 1250
页数:16
相关论文
共 16 条
[1]   H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].
BAX, A ;
SUMMERS, MF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2093-2094
[2]   SENSITIVITY-ENHANCED TWO-DIMENSIONAL HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY [J].
BAX, A ;
SUBRAMANIAN, S .
JOURNAL OF MAGNETIC RESONANCE, 1986, 67 (03) :565-569
[3]   PRACTICAL ASPECTS OF TWO-DIMENSIONAL TRANSVERSE NOE SPECTROSCOPY [J].
BAX, A ;
DAVIS, DG .
JOURNAL OF MAGNETIC RESONANCE, 1985, 63 (01) :207-213
[4]  
Benn M.H., 1983, ALKALOIDS CHEM BIOL, V1, P153
[5]   THE STRUCTURES OF CARDIONINE AND 11-ACETYLCARDIONINE, NEW C20-DITERPENOID ALKALOIDS, FROM THE SELECTIVE INAPT NMR TECHNIQUE [J].
DELAFUENTE, G ;
GAVIN, JA ;
REINA, M ;
ACOSTA, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (01) :342-344
[6]  
DENG YP, 1992, ACTA CHIM SINICA, V50, P822
[7]  
HANUMAN JB, 1994, PHYTOCHEMISTRY, V36, P1527, DOI 10.1016/S0031-9422(00)89756-3
[8]   ACONITUM .9. THE STRUCTURE OF PANICULATINE - A REVISION [J].
KATZ, A .
JOURNAL OF NATURAL PRODUCTS, 1989, 52 (02) :430-432
[9]   BARBISINE, A C-20-DITERPENOID ALKALOID FROM DELPHINIUM-BARBEYI [J].
KULANTHAIVEL, P ;
HOLT, EM ;
OLSEN, JD ;
PELLETIER, SW .
PHYTOCHEMISTRY, 1990, 29 (01) :293-295
[10]  
LI CJ, 1993, ACTA CHIM SINICA, V51, P915