Radicals in asymmetric organocatalysis

被引：52

作者：

Bertelsen, Soren ^{[1
]}

Nielsen, Martin ^{[1
]}

Jorgensen, Karl Anker ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, Danish Natl Res Fdn Ctr Catalysis, DK-8000 Aarhus C, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 39期

关键词：

asymmetric catalysis; carbonyl compounds; enamines; organocatalysis; radicals; RATE CONSTANTS; CHEMISTRY; CATALYSIS;

D O I：

10.1002/anie.200702834

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Radical turn to organocatalysis: Amino-catalysis has developed into a versatile tool for the stereoselective functionalization of carbonyl species. In the search for new organocatalytic transformations, attention has been focused on radicals to expand the scope of aminocatalysis. The successful application of the SOMO(singly occupied molecular orbital)-enamine activation has led to a number of novel transformations. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7356 / 7359

页数：4

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