Porous Porphyrin Nanoarchitectures on Surfaces

被引:74
作者
Makiura, Rie [1 ,2 ]
Kitagawa, Hiroshi [2 ,3 ]
机构
[1] Osaka Prefecture Univ, Nanosci & Nanotechnol Res Ctr, Osaka 5998570, Japan
[2] Japan Sci & Technol Agcy, CREST, Chiyoda Ku, Tokyo 1020075, Japan
[3] Kyoto Univ, Div Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan
基金
日本学术振兴会; 日本科学技术振兴机构;
关键词
Metal-organic frameworks; Coordination polymers; Porphyrinoids; Nanostructures; Thin films; LANGMUIR-BLODGETT-FILMS; SCANNING-TUNNELING-MICROSCOPY; MULTIPORPHYRIN ARRAYS; BUILDING-BLOCKS; METAL; PHTHALOCYANINE; FRAMEWORK; NETWORK; GROWTH; ARCHITECTURES;
D O I
10.1002/ejic.201000730
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Controlling the size and the growth direction of porous hybrid objects - metal-organic frameworks (MOFs) or porous coordination polymers (PCPs) - at the nanoscale is a critical issue for enabling their use in a number of potential applications that have arisen from the current remarkable activity in studying such porous materials. This microreview describes the recent progress in the design, growth, and characterization of multidimensional nanoarchitectures by employing porphyrin-based components. The versatility of the sequential bottom-up fabrication process, which uses multitopic molecular building units assembled by appropriately chosen linkers, is suitable to be extended to the formation of a rich variety of nanostructures endowed with pores on surfaces.
引用
收藏
页码:3715 / 3724
页数:10
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