The Intrinsic Kinetics and Heats of Reactions for Cellulose Pyrolysis and Char Formation

被引：79

作者：

Cho, Joungmo ^{[1
]}

Davis, Jeffrey M. ^{[1
]}

Huber, George W. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem Engn, Amherst, MA 01003 USA

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 10期

基金：

美国国家科学基金会;

关键词：

biomass; carbohydrates; cellulose; kinetics; pyrolysis; BIOMASS PYROLYSIS; MODEL; FUELS;

D O I：

10.1002/cssc.201000119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermochemical conversion of biomass starts with its pyrolysis. The intrinsic kinetics and heats of reactions for the three first reactions in cellulose pyrolysis are measured. The products from pyrolysis of cellulose can vary depending on the temperature of pyrolysis, with levoglucosan being formed at higher temperature. Furthermore, pyrolysis can be either exothermic or endothermic depending on the products formed. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1162 / 1165

页数：4

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