High pressure assisted 1,3-dipolar cycloadditions: Formation of 1,2,3-triazoles from aryl azides and (trimethylsilyl)acetylene

被引：12

作者：

Melai, V

Brillante, A

Zanirato, P

机构：

[1] Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy

[2] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 11期

关键词：

D O I：

10.1039/a804681f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cycloaddition of aryl azides to the corresponding 1,2,3-triazoles has been studied by means of FTIR spectroscopy in a diamond anvil cell at pressures up to 1 GPa. The rate of reaction increases logarithmically with pressure and the yield is close to quantitative.

引用

页码：2447 / 2449

页数：3

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