Constitution of Grignard reagent RMgCl in tetrahydrofuran

被引：99

作者：

Sakamoto, S

Imamoto, T ^{[1
]}

Yamaguchi, K

机构：

[1] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 2638522, Japan

[2] Chiba Univ, Fac Sci, Inage Ku, Chiba 2638522, Japan

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol010048x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The constitution of Grignard reagent, RMgCl (R = Me, tBu, Ph or benzyl), was investigated in the solid state by means of X-ray crystallography and in THF by coldspray ionization mass spectrometry (CSI-MS), Three types of crystal structures, (a) [Mg-2(mu -Cl-3)(THF)(6)]+. [RMgCl2(THF)](-), (b) R2Mg4Cl6(THF)(6), and (c) [2Mg(2)(mu -Cl-3)(THF)(6)](+.)[R4Mg2Cl2](2-), were identified, and MeMg2(mu -Cl-3)(THF)(4-6) were detected as major species of MeMgCl in solution.

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页码：1793 / 1795

页数：3

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