Polarized IR-microscope spectra of guanidinium hydrogenselenate single crystal

The polarized IR-microscope spectra of C(NH2)(3)(HSeO4)-H-. small single crystal samples were measured at room temperature. The spectra are discussed with the framework of oriented gas model approximation and group theory. The stretching vOH vibration of the hydrogen bond with the O (...) O distance of 2.616 angstrom gives characteristic broad AB-type absorption in the IR spectra. The changes of intensity of the AB bands in function of polarizer angle are described. Detailed assignment for bands derived from stretching and bending modes of selenate anions and guanidinium cations were performed. The observed intensities of these bands in polarized infrared spectra were correlated with theoretical calculation of directional cosines of selected transition dipole moments for investigated crystal. The vibrational studies seem to be helpful in understanding of physical and chemical properties of described compound and also in design of new complexes with exactly defined behaviors. (c) 2004 Elsevier B.V. All rights reserved.