Copper(II) adducts with N,N,N′,N′-tetramethylethane-1,2-diamine and attempts to prepare trinuclear derivatives

被引：28

作者：

Handley, DA ^{[1
]}

Hitchcock, PB ^{[1
]}

Lee, TH ^{[1
]}

Leigh, GJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANICA CHIMICA ACTA | 2001年 / 316卷 / 1-2期

关键词：

copper complexes; diamine complexes; trinuclear complexes; dinuclear complexes;

D O I：

10.1016/S0020-1693(01)00378-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have attempted to prepare complexes of the type [M3Cl5(tmen)(3)][BPh4] (tmen = Me2N(CH2)(2)NMe2) with M = Cu. Such species are already known for M = Ti, V, Fe, Ni, and Co, but we have been unable to prepare any Cu analogues. The [BPh4](-)appears to reduce Cu-II to Cu-I and we isolated the known [Cu(tmen)(2)][CuCl2] from reaction mixtures that contained it. Attempts to obviate this reduction by using a different anion were successful, but no triangulo species were isolated. However, during this work we isolated and structurally characterised [{CuF(BF4)(tmen)}(2)] and [{Cu(OH)(BF4)(tmen)}(2)]. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：59 / 64

页数：6

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