On the use of ligand field parameters in the study of coordinated water molecules in Eu3+ complexes

被引：15

作者：

Albuquerque, RQ

Freire, RO

Malta, OL

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[2] Univ Fed Pernambuco, CCEN, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2005年 / 109卷 / 20期

关键词：

D O I：

10.1021/jp050710x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new methodology is proposed by which the number of coordinated water molecules, n, can be estimated in Eu3+ complexes. It is based on a comparison between the theoretical and experimental Stark levels, the former being calculated by assuming that n varies from 0 to 4 and predicting the so-called ligand field parameters, B-q(k). The methodology, initially developed in the study of the Eu(pya)(3)center dot nH(2)O complex, has been applied successfully to beta-diketonate complexes of Eu3+, for which crystallographic and luminescence data are available.

引用

收藏

页码：4607 / 4610

页数：4

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