Selectivity for dinegative versus mononegative oxoanionic guests within a cryptand host

被引：51

作者：

Maubert, BM ^{[1
]}

Nelson, J

McKee, V

Town, RM

Pál, I

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

[2] Open Univ, Milton Keynes MK7 6AA, Bucks, England

[3] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 09期

关键词：

D O I：

10.1039/b101832i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the structures of three new oxoanion cryptates (M=Cr(VI), Se(VI) and SSO32-) of a protonated azacryptate host: H6L(MO42-)(ClO4)(4) the dinegative anion invariably occupies the crypt, providing evidence of selectivity with respect to the mononegative analogue; solution studies support this observation.

引用

页码：1395 / 1397

页数：3

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