Mossbauer evaluation of cobalt ferrite nanoparticles synthesized by forced hydrolysis

被引:26
作者
Hamdeh, HH [1 ]
Hikal, WM
Taher, SM
Ho, JC
Thuy, NP
Quy, OK
Hanh, N
机构
[1] Wichita State Univ, Dept Phys, Wichita, KS 67226 USA
[2] Int Training Inst Mat Sci, Hanoi, Vietnam
[3] Hanoi Univ Technol, Hanoi, Vietnam
关键词
D O I
10.1063/1.1856219
中图分类号
O59 [应用物理学];
学科分类号
摘要
Spinel cobalt ferrite in the form of nearly spherical particles, having a narrow range of particle size around 7.6 nm, was produced by forced hydrolysis. Between the magnetization blocking temperature of 180 K and the Mossbauer blocking temperature of 270 K, the magnetic anisotropy energy decreases rapidly with temperature. The occupancy of the octahedral sites by only half of the Co2+ cations may have weakened the crystalline anisotropy. Significant spin canting was also observed at these sites. (C) 2005 American Institute of Physics.
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页数:4
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