Formation of unsymmetrical polyoxotungstates via transfer of polyoxometalate building blocks.: NMR evidence supports the kinetic stability of the pentatungstate anion, [W5O18]6-, in aqueous solution

被引:25
作者
Belai, N [1 ]
Sadakane, M [1 ]
Pope, MT [1 ]
机构
[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA
关键词
D O I
10.1021/ja005578n
中图分类号
O6 [化学];
学科分类号
0703 ;
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页码:2087 / 2088
页数:2
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共 39 条
[1]   Lanthanide complexes of polyoxometalates: Characterization by tungsten-183 and phosphorus-31 nuclear magnetic resonance spectroscopy [J].
Bartis, J ;
Sukal, S ;
Dankova, M ;
Kraft, E ;
Kronzon, R ;
Blumenstein, M ;
Francesconi, LC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (11) :1937-1944
[2]   Lanthanide complexes of the α-1 isomer of the [P2W17O61]10- heteropolytungstate:: Preparation, stoichiometry, and structural characterization by 183W and 31P NMR spectroscopy and europium(III) luminescence spectroscopy [J].
Bartis, J ;
Dankova, M ;
Lessmann, JJ ;
Luo, QH ;
Horrocks, WD ;
Francesconi, LC .
INORGANIC CHEMISTRY, 1999, 38 (06) :1042-1053
[3]  
BOTAR AV, 1973, REV ROUM CHIM, V18, P1155
[4]  
Ciabrini J. -P., 1993, J CHEM RES M, P2720
[5]  
CIABRINI JP, 1993, J CHEM RES-S, P391
[6]   O-17, P-31 AND W-183 NMR-SPECTRA OF PARAMAGNETIC-COMPLEXES WITH THE HETEROPOLYTUNGSTATE ANION [LN(PW11O39)2]11- AND THEIR CONSTITUTION IN AQUEOUS-SOLUTION - LN RARE-EARTH ELEMENT [J].
FEDOTOV, MA ;
PERTSIKOV, BZ ;
DANOVICH, DK .
POLYHEDRON, 1990, 9 (10) :1249-1256
[7]  
Fedotov MA, 1996, POLYHEDRON, V15, P3341
[8]   CRYSTAL STRUCTURE OF SODIUM 12-NIOBOMANGANATE(4) NA12MNNB12O38.50H2O [J].
FLYNN, CM ;
STUCKY, GD .
INORGANIC CHEMISTRY, 1969, 8 (02) :335-&
[9]   Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems [J].
Hill, CL .
CHEMICAL REVIEWS, 1998, 98 (01) :1-2
[10]   HETEROPOLYTUNGSTATE COMPLEXES OF LANTHANOID ELEMENTS .3. CRYSTAL-STRUCTURE OF SODIUM DECATUNGSTOCERATE(IV)-WATER(1/30) [J].
IBALL, J ;
LOW, JN ;
WEAKLEY, TJR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (18) :2021-2024