[Pt2Cl2(μ2-O2)2([9]aneN3)2]Cl2:: A novel platinum(VI) dimer with two bridging peroxo ligands that provides insight into the mechanism of aerial oxidation of platinum(II)

被引：31

作者：

Davies, MS ^{[1
]}

Hambley, TW ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期

关键词：

D O I：

10.1021/ic9806479

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Pt2Cl2(mu(2)-O-2)(2)([9]aneN(3))(2)]Cl-2. 4H(2)O, formed by reaction of cis-[PtCl2(dmso)(2)] (dmso = dimethyl sulfoxide) and 1,4,7-triazacyclononane ([9]aneN(3)) under aerobic conditions in wet ethanol solution, is the first structurally characterized:Pt(IV) complex where two metal centers are bridged by two (mu(2)) peroxo ligands and only the second such transition metal complex.

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页码：5408 / +

页数：3

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