Studies on the mechanism of chemiluminescence: Synthesis and chemiluminescent properties of the 5-hydroperoxide analogue of coelenterate luciferin

被引：8

作者：

Teranishi, K

Hisamatsu, M

Yamada, T

机构：

[1] Faculty of Bioresources, Mie University, Kamihama, Tsu

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 46期

关键词：

D O I：

10.1016/0040-4039(96)01927-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 5-hydroperoxide analogue of coelenterate luciferin has been synthesized and is one of the postulated intermediates in chemiluminescent reactions of coelenterate luciferin, Cypridina luciferin, and its analogues. The 5-hydroperoxide analogue emitted weak light in chemiluminescent reactions in several solvent systems. However, it did pot generate any amide. This research leads to the conclusion that 5-hydroperoxide is not an important intermediate in chemiluminescent reactions. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：8425 / 8428

页数：4

共 28 条

[1] CHEMILUMINESCENCE OF CIPRIDINA LUCIFERIN ANALOGS .2. KINETIC-STUDIES ON THE REACTION OF 2-METHYL-6-PHENYLIMIDAZO[1,2-A]PYRAZIN-3(7H)-ONE (CLA) WITH SUPEROXIDE - HYDROPEROXYL RADICAL IS AN ACTUAL ACTIVE SPECIES USED TO INITIATE THE REACTION [J].