Solid-phase reaction synthesis of mesostructured tungsten disulfide material with a high specific surface area

被引：14

作者：

An, Gaojun ^{[1
]}

Lu, Changbo ^{[1
]}

Xiong, Chunhua ^{[1
]}

机构：

[1] Beijing POL Res Inst, Beijing 102300, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 2011年 / 46卷 / 09期

关键词：

Inorganic compounds; Nanostructures; Chemical synthesis; X-ray diffraction; Catalytic properties; IN-SITU ACTIVATION; WS2; CATALYSTS; TETRAALKYLAMMONIUM THIOTUNGSTATES; MOS2; AMMONIUM; THIOMOLYBDATES; NANOCLUSTERS; NANOSPHERES; MORPHOLOGY; HDS;

D O I：

10.1016/j.materresbull.2011.05.024

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A mesostructured tungsten disulfide (WS(2)) material was prepared through a solid-phase reaction utilizing ammonium tetrathiotungstate as the precursor and n-octadecylamine as the template. The as-synthesized WS(2) material was characterized by X-ray powder Diffraction (XRD), Low-temperature N(2) Adsorption (BET method), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). The characterization results indicate that the WS(2) material has the typical mesopore structure (3.7 nm) with a high specific surface area (145.9 m(2)/g), and large pore volume (0.18 cm(3)/g). This approach is novel, green and convenient. The plausible mechanism for the formation of the mesostructured WS(2) material is discussed herein. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1323 / 1326

页数：4

共 18 条

[1] Activation of tetraalkylammonium thiotungstates for the preparation of Ni-promoted WS2 catalysts [J].