Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer

被引:418
作者
Zhang, JP [1 ]
Lin, YY [1 ]
Zhang, WX [1 ]
Chen, XM [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Photoelect Mat & Technol, Guangzhou 510275, Peoples R China
关键词
D O I
10.1021/ja054913a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer [Ag6Cl(atz)4]·OH·6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption. Copyright © 2005 American Chemical Society.
引用
收藏
页码:14162 / 14163
页数:2
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