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Osmium(II) CNN pincer complexes as efficient catalysts for both asymmetric transfer and H2 hydrogenation of ketones
被引:123
作者
:
论文数:
引用数:
h-index:
机构:
Baratta, Walter
[
1
]
Ballico, Maurizio
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Ballico, Maurizio
[
1
]
Chelucci, Giorgio
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Chelucci, Giorgio
[
2
]
Siega, Katia
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Siega, Katia
[
1
]
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[
1
]
机构
:
[1]
Univ Udine, Dipartimento Sci & Technol Chim, I-33100 Udine, Italy
[2]
Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
来源
:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
|
2008年
/ 47卷
/ 23期
关键词
:
asymmetric catalysis;
hydrides;
hydrogen transfer;
hydrogenation;
osmium;
D O I
:
10.1002/anie.200800339
中图分类号
:
O6 [化学];
学科分类号
:
0703 ;
摘要
:
Catalysis at a pinch: Osmium CNN pincer complexes [OsCl(CNN)P2] (see graphic) are extremely active and productive catalysts for both the transfer and asymmetric hydrogenation of ketones (TOF ≈ 106 h -1 and TON ≈105). High enantioselectivity is achieved in the presence of only 0.005-0.002 mol% of the chiral osmium derivatives. [OsX(CNN)(dppb)] species with X = H and OR are involved in these catalytic TH and HY reactions. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4362 / 4365
页数:4
相关论文
共 34 条
[1]
THE OXIDATION POTENTIALS OF ALDEHYDES AND KETONES
ADKINS, H
论文数:
0
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0
h-index:
0
ADKINS, H
ELOFSON, RM
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0
引用数:
0
h-index:
0
ELOFSON, RM
ROSSOW, AG
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0
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0
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0
ROSSOW, AG
ROBINSON, CC
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0
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0
h-index:
0
ROBINSON, CC
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[Anonymous], 2007, HDB HOMOGENEOUS HYDR
[3]
Ruthenium(II) terdentate CNN complexes: Superlative catalysts for the hydrogen-transfer reduction of ketones by reversible insertion of a carbonyl group into the Ru-H bond
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Baratta, W
Chelucci, G
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Chelucci, G
Gladiali, S
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Gladiali, S
Siega, K
论文数:
0
引用数:
0
h-index:
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, K
Toniutti, M
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, M
Zanette, M
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0
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Zanette, M
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Zangrando, E
Rigo, P
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, P
[J].
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2-(Aminomethyl)pyridine-phosphine ruthenium(II) complexes: Novel highly active transfer hydrogenation catalysts
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Baratta, W
Herdtweck, E
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0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Herdtweck, E
Siega, K
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, K
Toniutti, M
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0
引用数:
0
h-index:
0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, M
Rigo, P
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引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, P
[J].
ORGANOMETALLICS,
2005,
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BARATTA W, 2005, ANGEW CHEM, V117, P6370
[6]
Osmium pyme complexes for fast hydrogenation and asymmetric transfer hydrogenation of ketones
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Baratta, Walter
Ballico, Maurizio
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Ballico, Maurizio
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Del Zotto, Alessandro
Siega, Katia
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0
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0
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0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
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Magnolia, Santo
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Magnolia, Santo
Rigo, Pierluigi
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0
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
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Fast and chemoselective transfer hydrogenation of aldehydes catalyzed by a terdentate CNN ruthenium complex [RuCl(CNN)(dppb)]
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, Katia
Rigo, Pierluigi
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0
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0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
ADVANCED SYNTHESIS & CATALYSIS,
2007,
349
(10)
: 1633
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1636
[8]
Catalytic transfer hydrogenation with terdentate CNN ruthenium complexes: The influence of the base
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Baratta, Walter
Siega, Katia
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0
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0
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0
机构:
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Siega, Katia
Rigo, Pierluigi
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Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
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Terdentate RuX(CNN)(PP) (X = Cl, H, OR) complexes: Synthesis, properties, and catalytic activity in fast transfer hydrogenation
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Baratta, Walter
Bosco, Marco
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0
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机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Bosco, Marco
Chelucci, Giorgio
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Chelucci, Giorgio
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Del Zotto, Alessandro
Siega, Katia
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0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, Katia
Toniutti, Micaela
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0
引用数:
0
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Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, Micaela
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h-index:
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Zangrando, Ennio
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
ORGANOMETALLICS,
2006,
25
(19)
: 4611
-
4620
[10]
Blaser H.U., 2004, ASYMMETRIC CATALYSIS
←
1
2
3
4
→
共 34 条
[1]
THE OXIDATION POTENTIALS OF ALDEHYDES AND KETONES
ADKINS, H
论文数:
0
引用数:
0
h-index:
0
ADKINS, H
ELOFSON, RM
论文数:
0
引用数:
0
h-index:
0
ELOFSON, RM
ROSSOW, AG
论文数:
0
引用数:
0
h-index:
0
ROSSOW, AG
ROBINSON, CC
论文数:
0
引用数:
0
h-index:
0
ROBINSON, CC
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1949,
71
(11)
: 3622
-
3629
[2]
[Anonymous], 2007, HDB HOMOGENEOUS HYDR
[3]
Ruthenium(II) terdentate CNN complexes: Superlative catalysts for the hydrogen-transfer reduction of ketones by reversible insertion of a carbonyl group into the Ru-H bond
论文数:
引用数:
h-index:
机构:
Baratta, W
Chelucci, G
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Chelucci, G
Gladiali, S
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Gladiali, S
Siega, K
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, K
Toniutti, M
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, M
Zanette, M
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Zanette, M
论文数:
引用数:
h-index:
机构:
Zangrando, E
Rigo, P
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, P
[J].
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,
2005,
44
(38)
: 6214
-
6219
[4]
2-(Aminomethyl)pyridine-phosphine ruthenium(II) complexes: Novel highly active transfer hydrogenation catalysts
论文数:
引用数:
h-index:
机构:
Baratta, W
Herdtweck, E
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Herdtweck, E
Siega, K
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, K
Toniutti, M
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, M
Rigo, P
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, P
[J].
ORGANOMETALLICS,
2005,
24
(07)
: 1660
-
1669
[5]
BARATTA W, 2005, ANGEW CHEM, V117, P6370
[6]
Osmium pyme complexes for fast hydrogenation and asymmetric transfer hydrogenation of ketones
论文数:
引用数:
h-index:
机构:
Baratta, Walter
Ballico, Maurizio
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Ballico, Maurizio
论文数:
引用数:
h-index:
机构:
Del Zotto, Alessandro
Siega, Katia
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, Katia
Magnolia, Santo
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Magnolia, Santo
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
CHEMISTRY-A EUROPEAN JOURNAL,
2008,
14
(08)
: 2557
-
2563
[7]
Fast and chemoselective transfer hydrogenation of aldehydes catalyzed by a terdentate CNN ruthenium complex [RuCl(CNN)(dppb)]
论文数:
引用数:
h-index:
机构:
Baratta, Walter
Siega, Katia
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, Katia
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
ADVANCED SYNTHESIS & CATALYSIS,
2007,
349
(10)
: 1633
-
1636
[8]
Catalytic transfer hydrogenation with terdentate CNN ruthenium complexes: The influence of the base
论文数:
引用数:
h-index:
机构:
Baratta, Walter
Siega, Katia
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Siega, Katia
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Univ Udine, Dipartimento Sci & Technol Chem, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
CHEMISTRY-A EUROPEAN JOURNAL,
2007,
13
(26)
: 7479
-
7486
[9]
Terdentate RuX(CNN)(PP) (X = Cl, H, OR) complexes: Synthesis, properties, and catalytic activity in fast transfer hydrogenation
论文数:
引用数:
h-index:
机构:
Baratta, Walter
Bosco, Marco
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Bosco, Marco
Chelucci, Giorgio
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Chelucci, Giorgio
论文数:
引用数:
h-index:
机构:
Del Zotto, Alessandro
Siega, Katia
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Siega, Katia
Toniutti, Micaela
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Toniutti, Micaela
论文数:
引用数:
h-index:
机构:
Zangrando, Ennio
Rigo, Pierluigi
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Udine, Dipartimento Sci & Tecnol Chim, I-33100 Udine, Italy
Rigo, Pierluigi
[J].
ORGANOMETALLICS,
2006,
25
(19)
: 4611
-
4620
[10]
Blaser H.U., 2004, ASYMMETRIC CATALYSIS
←
1
2
3
4
→