New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity

被引：35

作者：

Fritsch, Julia ^{[1
]}

Rose, Marcus ^{[1
]}

Wollmann, Philipp ^{[1
]}

Boehlmann, Winfried ^{[2
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany

[2] Univ Leipzig, Fac Phys & Earth Sci, D-04103 Leipzig, Germany

来源：

MATERIALS | 2010年 / 3卷 / 04期

关键词：

element organic frameworks; EOF; heterogeneous catalysis; POLYMERS; ALDEHYDES; NETWORKS;

D O I：

10.3390/ma3042447

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m(2) g(-1) and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of materials might be able to replace common homogeneous element-organic and often highly toxic catalysts especially in the food industry.

引用

页码：2447 / 2462

页数：16

共 22 条

[1]

[Anonymous], HDB POROUS SOLIDS

[2] VIBRATIONAL-SPECTRA AND DIHEDRAL ANGLES OF BIPHENYL AND 4,4-DIHALOGENOBIPHENYLS [J].

BARRETT, RM ;

STEELE, D .

JOURNAL OF MOLECULAR STRUCTURE, 1972, 11 (01) :105-&

[3] Pathways for decomposition of THF by organolithiums: the role of HMPA [J].

Clayden, J ;

Yasin, SA .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (02) :191-192

[4] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[5] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[6] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[8]

Goyer R.A., 1996, CASARETT DOULLS TOXI

[9] Catalytic properties of MIL-101 [J].

Henschel, Antje ;

Gedrich, Kristina ;

Kraehnert, Ralph ;

Kaskel, Stefan .

CHEMICAL COMMUNICATIONS, 2008, (35) :4192-4194

[10]

Hesse M., 2005, SPEKTROSKOPISCHE MET

← 1 2 3 →