Manipulation of optical properties of Ag/Cu alloy nanowire arrays embedded in anodic alumina membranes

被引:8
作者
Hu, Xiaoye [1 ]
Wang, Zhenyang [2 ]
Zhang, Tianci [1 ]
Zeng, Xiaoyan [1 ]
Xu, Wei [1 ]
Zhang, Junxi [1 ]
Yan, Jian [1 ]
Zhang, Jinping [1 ]
Zhang, Lide [1 ]
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Hefei 230031, Peoples R China
[2] Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China
关键词
Ag/Cu nanowires; surface plasma resonance; redshift; electrodeposition;
D O I
10.1016/j.apsusc.2007.12.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Arrays of Ag/Cu alloy nanowires embedded in anodic alumina membranes (AAMs) were synthesized by directly electrodepositing from a mixing electrolyte solution containing Ag+ and Cu2+ ions. Manipulations of optical properties of the resulting samples were successfully achieved by tuning the molar ratio of Ag+ and Cu2+ ions in the starting materials. When the ratio is less than 2:20, two surface plasma resonance (SPR) peaks corresponding to Ag and Cu appear, respectively. After annealing treatment, the SPR peak corresponding to Cu disappears, and that of Ag presents a red shift. Furthermore, this red shift can be up to 85 nm when the molar ratio of Ag+ and Cu2+ reduce to 1: 20, which is attributed to the transferable electrons from Cu atoms. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:3845 / 3848
页数:4
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