Aqueous catalysis by novel macromolecule metal complexes with molecular recognition abilities

被引：23

作者：

Karakhanov, EA ^{[1
]}

Kardasheva, YS ^{[1
]}

Maximov, AL ^{[1
]}

Runova, EA ^{[1
]}

Buchneva, TA ^{[1
]}

Gaevskiy, MA ^{[1
]}

Zhuchkova, AY ^{[1
]}

Filippova, TY ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2001年 / 12卷 / 3-4期

关键词：

macromolecular metal complexes; supramolecular catalysis; aqueous catalysis; cyclodextrins; calixarenes;

D O I：

10.1002/pat.140

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A number of water-soluble macromolecular metal complexes on the basis of polyethers, beta -cyclodextrins, calix[4] and calix[6]arenes functionalized by oligoethylene oxide blocks, catechol, ethylendiamine, acetylacetone, 2,2'-dipiridyl, phosphines and nitrile containing groups have been developed. Complexes showed high catalytic activity in aqueous hydroformylation, biphasic Wacker-type oxidation of various higher olefines, alkane oxidation, hydroxylation of benzene and phenol. These catalysts can be multiply reused. The application of host compounds results the extremely selectivities. Copyright (C) 2001 John Wiley & Sons, Ltd.

引用

页码：161 / 168

页数：8

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