A robust and efficient cobalt molecular catalyst for CO2 reduction

被引：125

作者：

Chan, Sharon Lai-Fung ^{[1
,2
]}

Lam, Tsz Lung ^{[1
,2
]}

Yang, Chen ^{[3
,4
,5
]}

Yan, Siu-Cheong ^{[1
,2
]}

Cheng, Nga Man ^{[1
,2
]}

机构：

[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

[2] Hong Kong Polytech Univ, Shenzhen Res Inst, Shenzhen, Peoples R China

[3] Chinese Acad Sci, Joint Lab New Mat, HKU, Hong Kong, Hong Kong, Peoples R China

[4] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[5] Chinese Acad Sci, Joint Lab New Mat, Inst Mol Funct Mat, State Key Lab Synth Chem,HKU, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 37期

基金：

美国国家科学基金会;

关键词：

VISIBLE-LIGHT; CARBON-DIOXIDE; HYDROGEN; COMPLEX; WATER; ACTIVATION; MONOXIDE; LIGANDS;

D O I：

10.1039/c5cc00566c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible-light driven CO2 reduction is considered to be a sustainable energy source. However, earth-abundant molecular catalysts with high efficiency and robustness towards solar-driven CO2 reduction are limited. Herein, we report a cobalt complex supported by a tetradentate tripodal ligand, which demonstrates catalytic solardriven CO2 reduction with TON(CO) > 900 over 70 h in the presence of a photosensitizer.

引用

页码：7799 / 7801

页数：3

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