Characterization of biomass pyrolysis vapors with molecular beam, single photon ionization time-of-flight mass spectrometry

被引：37

作者：

Brown, AL

Dayton, DC

Nimlos, MR

Daily, JW

机构：

[1] Natl Renewable Energy Lab, Golden, CO 80401 USA

[2] Univ Colorado, Dept Mech Engn, Ctr Combust Res, Boulder, CO 80309 USA

来源：

CHEMOSPHERE | 2001年 / 42卷 / 5-7期

关键词：

aspen; polystyrene; cellulose; fragmentation;

D O I：

10.1016/S0045-6535(00)00240-X

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A single photon ionization, molecular beam sampling, reflection time-of-flight mass spectrometer (SPI/MBTOFMS) has been developed and used to study pyrolysis products from a selection of biomass materials. Spectra are characterized by high resolution and decreased fragmentation compared to electron-impact ionization mass spectra from related molecular beam mass spectrometer systems equipped with quadrupole mass analyzers. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：663 / 669

页数：7

共 29 条

[1] CELLULOSE PYROLYSIS KINETICS - THE CURRENT STATE KNOWLEDGE
ANTAL, MJ
VARHEGYI, G
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (03) : 703 - 717
[2] MULTI-PHOTON MASS-SPECTROMETRY OF METASTABLES - DIRECT OBSERVATION OF DECAY IN A HIGH-RESOLUTION TIME-OF-FLIGHT INSTRUMENT
BOESL, U
NEUSSER, HJ
WEINKAUF, R
SCHLAG, EW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (25) : 4857 - 4863
[3] Real-time determination of aromatics in automobile exhaust by single photon ionisation ion trap mass spectrometry
Butcher, DJ
Goeringer, DE
Hurst, GB
[J]. ANALYTICAL CHEMISTRY, 1999, 71 (02) : 489 - 496
[4] Release of inorganic constituents from leached biomass during thermal conversion
Dayton, DC
Jenkins, BM
Turn, SQ
Bakker, RR
Williams, RB
Belle-Oudry, D
Hill, LM
[J]. ENERGY & FUELS, 1999, 13 (04) : 860 - 870
[5] DIRECT OBSERVATION OF ALKALI VAPOR RELEASE DURING BIOMASS COMBUSTION AND GASIFICATION .1. APPLICATION OF MOLECULAR-BEAM MASS-SPECTROMETRY TO SWITCHGRASS COMBUSTION
DAYTON, DC
FRENCH, RJ
MILNE, TA
[J]. ENERGY & FUELS, 1995, 9 (05) : 855 - 865
[6] DeSollar, 1996, APPL ADV TECHNOLOGY, P161
[7] MOLECULAR CHARACTERIZATION OF THE PYROLYSIS OF BIOMASS .2. APPLICATIONS
EVANS, RJ
MILNE, TA
[J]. ENERGY & FUELS, 1987, 1 (04) : 311 - 319
[8] MASS-SPECTROMETRIC BEHAVIOR OF LEVOGLUCOSAN UNDER DIFFERENT IONIZATION CONDITIONS AND IMPLICATIONS FOR STUDIES OF CELLULOSE PYROLYSIS
EVANS, RJ
MILNE, TA
SOLTYS, MN
SCHULTEN, HR
[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1984, 6 (03) : 273 - 283
[9] MOLECULAR CHARACTERIZATION OF THE PYROLYSIS OF BIOMASS .1. FUNDAMENTALS
EVANS, RJ
MILNE, TA
[J]. ENERGY & FUELS, 1987, 1 (02) : 123 - 137
[10] On-line emission analysis of polycyclic aromatic hydrocarbons down to pptv concentration levels in the flue gas of an incineration pilot plant with a mobile resonance enhanced multiphoton ionization time-of-flight mass spectrometer
Heger, HJ
Zimmermann, R
Dorfner, R
Beckmann, M
Griebel, H
Kettrup, A
Boesl, U
[J]. ANALYTICAL CHEMISTRY, 1999, 71 (01) : 46 - 57

← 1 2 3 →