Preparation of soluble polyimide-silver nanocomposites by a convenient ultraviolet irradiation technique

被引:33
作者
Huang, JC [1 ]
Qian, XF [1 ]
Yin, J [1 ]
Zhu, ZK [1 ]
Xu, HJ [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
关键词
nanocomposites; polyimide; silver; ultraviolet irradiation;
D O I
10.1016/S0254-0584(00)00392-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The soluble polyimide (PI)-silver nanocomposites were synthesized successfully by a novel convenient ultraviolet irradiation technique. Two precursors (AgAc, AgNO3) were used as the sources of the silver particles. Transmission electron microcopy showed that two types of silver particles with diameters of 6-10 and 15-20 nm, respectively, were homogeneously dispersed in the PI matrix. X-ray diffraction results were well corresponding to the size of the smaller silver particles, and the larger silver particles may be the aggregates of the smaller ones. The absorption peaks due to the surface plasmon resonance of the silver particles in the two PI-silver nanocomposites was observed at 420-430 nm in the ultraviolet-visible (UV-VIS) absorption spectra. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:172 / 175
页数:4
相关论文
共 18 条
[1]   DEGENERATE 4-WAVE MIXING IN COLLOIDAL GOLD AS A FUNCTION OF PARTICLE-SIZE [J].
BLOEMER, MJ ;
HAUS, JW ;
ASHLEY, PR .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1990, 7 (05) :790-795
[2]   THE OPTICAL KERR EFFECT IN SMALL METAL PARTICLES AND METAL COLLOIDS - THE CASE OF GOLD [J].
HACHE, F ;
RICARD, D ;
FLYTZANIS, C ;
KREIBIG, U .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1988, 47 (04) :347-357
[3]  
HACHE F, 1986, J OPT SOC AM B, V3, P1847
[4]   QUANTUM SIZE EFFECTS IN METAL PARTICLES [J].
HALPERIN, WP .
REVIEWS OF MODERN PHYSICS, 1986, 58 (03) :533-606
[6]   Ag precipitation and optical behavior in Na2O-B2O3 glasses [J].
Itoigawa, H ;
Kamiyama, T ;
Nakamura, Y .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 220 (2-3) :210-216
[7]   COLLOIDAL GOLD DISPERSIONS IN POLYMERIC MATRICES [J].
KUNZ, MS ;
SHULL, KR ;
KELLOCK, AJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1993, 156 (01) :240-249
[8]   CHEMICAL CATALYSIS BY COLLOIDS AND CLUSTERS [J].
LEWIS, LN .
CHEMICAL REVIEWS, 1993, 93 (08) :2693-2730
[9]  
Lu QH, 1999, J APPL POLYM SCI, V72, P1299, DOI 10.1002/(SICI)1097-4628(19990606)72:10<1299::AID-APP9>3.3.CO
[10]  
2-A