On the importance of hydroxyl groups in the polar head-group of nonionic surfactants and membrane lipids

被引:90
作者
Shinoda, K
Carlsson, A
Lindman, B
机构
[1] SCOTIA LIPID TEKN AB,S-11384 STOCKHOLM,SWEDEN
[2] LUND UNIV,CTR CHEM,S-22100 LUND,SWEDEN
关键词
D O I
10.1016/0001-8686(95)00287-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this review properties of natural membrane lipids and surfactants synthesized from natural substances, such as paraffin chain alcohols and carbohydrates, are compared with those of synthetic surfactants of the polyoxyethylene type. Special attention is paid to the characteristic solution properties of nonionic surfactants with hydroxyl groups as the hydrophilic moiety, including alkyl glyceryl ethers and alkyl glucosides and maltosides, which are compared with those with oxyethylene groups. The major properties of the hydrophilic moiety are lipophobicity and hydrophilicity. Lipophobicity is an important property of oil-soluble surfactants, in particular for the polyoxyethylene alkyl ether type of surfactants where a too high lipophobicity may result in solubility in water.
引用
收藏
页码:253 / 271
页数:19
相关论文
共 25 条
[1]  
CARLSSON A, IN PRESS
[2]   PERMEABILITY OF LIPOSOMES COMPOSED OF BINARY-MIXTURES OF MONOGALACTOSYLDIACYLGLYCEROL AND DIGALACTOSYLDIACYLGLYCEROL [J].
FOLEY, AA ;
BRAIN, APR ;
QUINN, PJ ;
HARWOOD, JL .
BIOCHIMICA ET BIOPHYSICA ACTA, 1988, 939 (03) :430-440
[3]  
ISHIZUKA I, 1985, GLYCOLIPIDS, pCH2
[4]   OAT LIPIDS - INTERACTION WITH WATER AND CHARACTERIZATION OF AQUEOUS PHASES [J].
JAYASINGHE, G ;
LARSSON, K ;
MIEZIS, Y ;
SIVIK, B .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 1991, 12 (5-6) :443-451
[5]  
KAMEGAI J, 1987, CHEM EXPRESS, V2, P85
[6]   SOLUBILITY OF ALCOHOLS IN WATER DETERMINED BY THE SURFACE TENSION MEASUREMENTS [J].
KINOSHITA, K ;
ISHIKAWA, H ;
SHINODA, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1958, 31 (09) :1081-1082
[7]  
LANG JC, 1980, J CHEM PHYS, V73, P5489
[8]   COMPARATIVE ACUTE TOXICITIES OF SURFACTANTS TO AQUATIC INVERTEBRATES [J].
LEWIS, MA ;
SUPRENANT, D .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 1983, 7 (03) :313-322
[9]   SURFACE-ACTIVITIES, BIODEGRADABILITY AND ANTIMICROBIAL PROPERTIES OF NORMAL-ALKYL GLUCOSIDES, MANNOSIDES AND GALACTOSIDES [J].
MATSUMURA, S ;
IMAI, K ;
YOSHIKAWA, S ;
KAWADA, K ;
UCHIBORI, T .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1990, 67 (12) :996-1001
[10]  
SAIJO H, 1990, 22 CLEAN S JAP TOK