Gold on Diamond Nanoparticles as a Highly Efficient Fenton Catalyst

被引：230

作者：

Navalon, Sergio ^{[1
]}

Martin, Roberto ^{[1
]}

Alvaro, Mercedes ^{[1
]}

Garcia, Hermenegildo ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Dept Quim, Valencia 46022, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 45期

关键词：

Fenton reaction; gold; heterogeneous catalysis; nanoparticles; radical reactions; LOW-TEMPERATURE OXIDATION; PEROXIDE OXIDATION; WET; DEGRADATION; PARAMETERS; ALCOHOLS; HYDROGEN; OXIDE; CO;

D O I：

10.1002/anie.201003216

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Nanojewels as catalysts: Degradation of phenol with a small excess of H2O2 can be achieved by using gold nanoparticles supported on Fenton-treated diamond nanoparticles as a highly selective (at least 79 %) and efficient (turnover number: 321 000) catalyst for the Fenton reaction at room temperature. The proposed mechanism is shown schematically in the picture. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8403 / 8407

页数：5

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