New approach to CF3-containing polysubstituted anilines:: reaction of β-trifluoroacetylvinyl ethers with enamines

被引：36

作者：

Volochnyuk, DM ^{[1
]}

Kostyuk, AN ^{[1
]}

Sibgatulin, DA ^{[1
]}

Chernega, AN ^{[1
]}

Pinchuk, AM ^{[1
]}

Tolmachev, AA ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine

来源：

TETRAHEDRON | 2004年 / 60卷 / 10期

关键词：

beta-trifluoroacetylvinyl ethers; 'push-pull' enamines; trifluoromethyl; arene hydrates;

D O I：

10.1016/j.tet.2004.01.010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of beta-trifluoroacetylvinyl ethers with 'push-pull' enamines having a methyl group at the alpha-position was investigated. As a result, a set of CF3-containing dialkyl anilines and their covalent hydrates were obtained. A possible reaction mechanism and the stability of the covalent hydrates obtained are discussed. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2361 / 2371

页数：11

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