NH3 selective catalytic reduction (SCR) of nitrogen oxides (NOx) over activated sewage sludge char

被引:49
作者
Jo, Yong Beom [1 ]
Cha, Jin Sun [2 ]
Ko, Jeong Huy [1 ]
Shin, Min Chul [3 ]
Park, Sung Hoon [4 ]
Jeon, Jong-Ki [5 ]
Kim, Seung-Soo [6 ]
Park, Young-Kwon [1 ,2 ]
机构
[1] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea
[2] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea
[3] Mat Testing Ctr, Korea Testing Lab, Seoul 152718, South Korea
[4] Sunchon Natl Univ, Dept Environm Engn, Sunchon 540742, South Korea
[5] Kongju Natl Univ, Dept Chem Engn, Cheonan 330717, South Korea
[6] Kangwon Natl Univ, Dept Chem Engn, Samcheok 245711, South Korea
关键词
Sewage Sludge Char; De-NOx Physical Activation; Chemical Activation; LOW-TEMPERATURE SCR; CHEMICAL ACTIVATION; CARBON; PERFORMANCE; REMOVAL; FE;
D O I
10.1007/s11814-010-0283-7
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
The de-NOx performance of sewage sludge chars activated physically using water vapor or chemically using KOH was evaluated. Characteristics of chars activated under different activation temperatures, water vapor concentrations, and KOH/char ratios were analyzed by N-2 adsorption-desorption and FT-IR. Chemically activated chars were more efficient in removing NO, due to their higher surface area, oxygen functional group and NH3 adsorption than physically activated chars. The de-NO performance of the activated chars is influenced more by chemical properties such as oxygen functional groups and NH3 adsorption sites than by physical properties like specific surface area and pore volume.
引用
收藏
页码:106 / 113
页数:8
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