An outline of new calculation methods for the determination of both thermodynamic and kinetic parameters from isothermal heat conduction microcalorimetry

被引:15
作者
Beezer, AE [1 ]
机构
[1] NRI Univ Greenwich, Chatham ME4 4TB, Kent, England
关键词
calorimetry; thermodynamics; kinetics; equilibrium;
D O I
10.1016/S0040-6031(01)00673-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
An outline of equations allowing calculation, from calorimetric data, of both thermodynamic and kinetic parameters for reactions which proceed to completion is given. In addition equilibrium constants are calculable for reactions which proceed to an equilibrium position. Advantages of the methods for solid state kinetic and stability studies are briefly discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:205 / 208
页数:4
相关论文
共 12 条
[1]
Direct determination of equilibrium thermodynamic and kinetic parameters from isothermal heat conduction microcalorimetry [J].
Beezer, AE ;
Morris, AC ;
O'Neill, MAA ;
Willson, RJ ;
Hills, AK ;
Mitchell, JC ;
Connor, JA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06) :1212-1215
[2]
BEEZER AE, 2001, IN PRESS THERMOCHIM
[3]
Thermodynamic and kinetic analysis of isothermal microcalorimetric data: applications to consecutive reaction schemes [J].
Gaisford, S ;
Hills, AK ;
Beezer, AE ;
Mitchell, JC .
THERMOCHIMICA ACTA, 1999, 328 (1-2) :39-45
[4]
GAISFORD S, 1998, THESIS U KENT
[6]
Hills A. K., 2001, THESIS U KENT
[7]
The imidazole catalysed hydrolysis of triacetin: a medium term chemical calibrant for isothermal microcalorimeters [J].
Willson, RJ ;
Beezer, AE ;
Hills, AK ;
Mitchell, JC .
THERMOCHIMICA ACTA, 1999, 325 (02) :125-132
[8]
Solid state reactions studied by isothermal microcalorimetry; The solid state oxidation of ascorbic acid [J].
Willson, RJ ;
Beezer, AE ;
Mitchell, JC .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 1996, 132 (1-2) :45-51
[9]
DETERMINATION OF THERMODYNAMIC AND KINETIC-PARAMETERS FROM ISOTHERMAL HEAT-CONDUCTION MICROCALORIMETRY - APPLICATIONS TO LONG-TERM-REACTION STUDIES [J].
WILLSON, RJ ;
BEEZER, AE ;
MITCHELL, JC ;
LOH, W .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (18) :7108-7113
[10]
WILLSON RJ, 1995, THERMOCHIM ACTA, V264, P27