A local fluctuation theorem

被引:44
作者
Ayton, G
Evans, DJ
Searles, DJ
机构
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
[2] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia
关键词
D O I
10.1063/1.1385158
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fluctuation theorem gives an analytic expression for the probability, in a nonequilibrium system of finite size observed for a finite time, that the dissipative flux will flow in the reverse direction to that required by the second law of thermodynamics. In the present paper a local version of the fluctuation theorem (LFT) is derived heuristically. We find that in the case of planar Poiseuille flow of a Newtonian fluid between thermostated walls, nonequilibrium molecular dynamics simulation results support our proposed LFT. (C) 2001 American Institute of Physics.
引用
收藏
页码:2033 / 2037
页数:5
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