Efficient preparation and resolution of trans-1,2-cyclobutanedicarboxylic acid and some of its derivatives

被引：7

作者：

Brunet, JJ

Herbowski, A

Neibecker, D

机构：

[1] UNIV TOULOUSE 3,CNRS,CHIM COORDINAT LAB,UNITE 8241,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 03期

关键词：

D O I：

10.1080/00397919608003639

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The readily available cis/trans mixture of 1,2-cyclobutanedicarboxylic acid undergoes a quantitative isomerization in 12N HCl to the trans-diacid (as monitored by NMR spectroscopy). The latter is resolved to the (+)- and (-)-trans-diacids by modified literature and patented methods. The synthesis of the (S,S)-(-)-trans-diol and (S,S)-(+)-trans-ditosylate from the (S,S)-(+)-trans-diacid is also reported.

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页码：483 / 493

页数：11

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