Different types of starch were processed in blend systems with natural plasticizers and commercial fibres by conventional extrusion and injection moulding techniques. Processing conditions and product qualities differed widely according to the kind of starches and additives used. Starch polymer characteristics, i.e. amylose/amylopectin ratio and molecular mass distribution, were studied in native and extruded samples in order to reveal structural effects on product quality. As a result it could be shown that thermomechanical treatments of starch caused significant depolymerization, especially of the amylopectin fraction, while the amylose fraction remained stable. Considerable improvements in product properties were achieved by adding small amounts of fibres to the starch samples. Blend systems with 2-7% fibres resulted in an increase of tensile strength and water resistance of these products. (C) 1998 Elsevier Science Limited. All rights reserved.